Chimezie Frank Onwudinjo
Title: Synthesis and characterization of Lithium orthosilicate
Abstract:
Lithium-ion batteries (LIB) have found their way in every aspect of our daily activities and operations due to their energy storage capacity and lower global warming potential. Despite the obvious advantage, the issue remains electronic waste management at end-of-life. Most of the spent LIBs are dumped in landfills constituting potential negative environmental impacts such as heavy metal contamination of groundwater table, soil contamination and damage to human organs arising from bioaccumulation. While efforts have been made towards waste management, the conversion of spent LIB to useful materials remains under-explored. The present study explores a novel way for the synthesis and characterization of lithium orthosilicate (Li4SiO4) using spent LIB as precursor. The study provides an opportunity to convert electronic wastes into a sorbent material for mitigating climate change. The produced Li4SiO4 samples were characterized by BET, XRD, ICP-MS, FTIR, SEM analyses to help understand the structure and composition. Furthermore, the material was treated for CO2 capture in a TGA. Our findings demonstrated that the prepared material is Li4SiO4 and an environmentally friendly and low-cost preparation method. Furthermore, the material showed promising results for CO2 capture with a BET surface area ranging from 2.5 – 5 m2/g. These results are significantly important in furtherance of research on carbon capture, utilization and storage.